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Triazabicyclodecene ( 1,5,7-triazabicyclo [4.4.0]dec-5-ene or TBD) is an organic compound consisting of a bicyclic guanidine. For a charge-neutral compound, it is a relatively strong base that is effective for a variety of organic transformations. TBD is colorless solid that is soluble in a variety of solvents. [4]
Infobox references. 1,8-Diazabicyclo [5.4.0]undec-7-ene, or more commonly DBU, is a chemical compound and belongs to the class of amidine compounds. It is used in organic synthesis as a catalyst, a complexing ligand, and a non-nucleophilic base. [3]
Pennsylvania Railroad class J1. Water cap. 124 scrapped, 6435 rumored to still extant but not confirmed. The PRR J1 was a class of 2-10-4 "Texas" type steam locomotives built between 1942 and 1944. The J1 had over 95,000 pounds-force (422.6 kN) of tractive effort, plus an additional 15,000 lbf (66.7 kN) if the booster engine was used.
Most 10 coupled engines constructed for U.S. railroads during World War I were of the USRA 2-10-2 arrangement, but the PRR committed to 122 of the 2-10-0s. [6] [7] Swengel argued this commitment to the 2-10-0, nicknamed "Deks", was controversial even in 1916 and was more so in 1922 when the PRR placed additional orders. The PRR was soon the ...
0%. It's important to note that the 3% minimum down payment for conventional loans is mainly for first-time homebuyers. If you've owned a home in the past three years, the minimum is generally 5% ...
Infobox references. 1,5-Diazabicyclo [4.3.0]non-5-ene (DBN) is a chemical compound with the formula C 7 H 12 N 2. [ 1] It is an amidine base used in organic synthesis. A related compound with related functions is 1,8-diazabicyclo [5.4.0]undec-7-ene (DBU). The relatively complex nature of the formal names for DBU and DBN (hence the common use of ...
Buchner ring expansion. The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in the second step, with an electrocyclic reaction opening the cyclopropane ...
USRA Light Santa Fe. Factor of adh. The USRA Light Santa Fe was a USRA standard class of steam locomotive designed under the control of the United States Railroad Administration, the nationalized railroad system in the United States during World War I. These locomotives were of 2-10-2 wheel arrangement in the Whyte notation, or 1′E1′ in UIC ...