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The Shapiro reaction or tosylhydrazone decomposition is an organic reaction in which a ketone or aldehyde is converted to an alkene through an intermediate hydrazone in the presence of 2 equivalents of organolithium reagent. [1][2][3] The reaction was discovered by Robert H. Shapiro in 1967. [4] The Shapiro reaction was used in the Nicolaou ...
The following is a list of affiliates with the former ACC Network, an ad hoc syndicated sports network operated by Raycom Sports and featuring the athletic teams of the Atlantic Coast Conference. This network is not to be confused with the ACC Network linear channel (announced on July 21, 2016 by the league and ESPN) which launched in 2019. [ 1]
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The Nicolaou Taxol total synthesis, published by K. C. Nicolaou and his group in 1994 concerns the total synthesis of taxol. [1] Taxol is an important drug in the treatment of cancer but also expensive because the compound is harvested from a scarce resource, namely the pacific yew. This synthetic route to taxol is one of several; other groups ...
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[9] When derived from hydrazine itself, hydrazones condense with a second equivalent of a carbonyl to give azines: [10] R 2 C=N−NH 2 + R 2 C=O → R 2 C=N−N=CR 2 + H 2 O. Hydrazones are intermediates in the Wolff–Kishner reduction. Hydrazones are reactants in hydrazone iodination, the Shapiro reaction, and the Bamford–Stevens reaction ...
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